How you initially configure the Enterprise Edition of Right Click Tools depends on whether you've installed it with Recast Management Server or as a Standalone application.
Right Click Tools Enterprise with Recast Management Server
After installing Right Click Tools Enterprise with Recast Management Server, you'll need to configure some options in the Recast Management Server interface. This includes adding new AD users and/or user groups, as well as setting up a route.
Recommended Configuration Workflow
2. Configure a Recast Proxy to manage tasks, making sure basic permissions are in place.
3. Add Active Directory Domains.
4. Add SMS Provider and Site Code.
Right Click Tools Enterprise Standalone
See Configuration Basics for Right Click Tools Standalone.